[{"command":"insert","method":null,"selector":".course-modal-ajax-placeholder-952485","data":"\u003Cdiv class=\u0022container content-rte\u0022\u003E\n  \u003Cdiv class=\u0022row\u0022\u003E\n    \u003Cdiv class=\u0022box col-md-6 bg-primary text-white\u0022\u003E\n      \u003Ch2 class=\u0022h1 text-left\u0022\u003E  Solution Chemistry 1: Speciation and process\n\u003C\/h2\u003E\n                  \u003Cdiv class=\u0022field-spacing\u0022\u003E\n        \u003Cdiv class=\u0022field__label h3 dash\u0022\u003EECTS :\n          3\n        \u003C\/div\u003E\n      \u003C\/div\u003E\n                  \u003Cdiv class=\u0022field-spacing\u0022\u003E\n        \u003Cdiv class=\u0022field__label h3 dash\u0022\u003ESemestre calendaire :\n          Semestre 1\n        \u003C\/div\u003E\n      \u003C\/div\u003E\n            \u003Cdiv class=\u0022field-spacing\u0022\u003E\n      \u003Cdiv class=\u0022field__label h3 dash\u0022\u003ED\u00e9tail du volume horaire\u003C\/div\u003E\n                        \u003Cdiv class=\u0022mt-5 text-justify\u0022\u003E\n                          \u003Cspan class=\u0022field__label h4 mt-5 \u0022\u003ECours magistraux :\u003C\/span\u003E\n                                      \u003Cspan\u003E20\u003C\/span\u003E\n                      \u003C\/div\u003E\n                                              \u003Cdiv class=\u0022mt-5 text-justify\u0022\u003E\n                          \u003Cspan class=\u0022field__label h4 mt-5 \u0022\u003ETravaux dirig\u00e9s :\u003C\/span\u003E\n                                      \u003Cspan\u003E10\u003C\/span\u003E\n                      \u003C\/div\u003E\n                                                            \u003C\/div\u003E\n        \u003Cdiv class=\u0022field-spacing\u0022\u003E\n      \u003Cdiv class=\u0022field__label h3 dash\u0022\u003ELangue d\u0026#039;enseignement\u003C\/div\u003E\n                        \u003Cdiv class=\u0022mt-5 text-justify\u0022\u003E\n                                      \u003Cspan\u003EAnglais\u003C\/span\u003E\n                      \u003C\/div\u003E\n                  \u003C\/div\u003E\n        \u003Cdiv class=\u0022field-spacing\u0022\u003E\n      \u003Cdiv class=\u0022field__label h3 dash\u0022\u003EEnseignement \u00e0 distance\u003C\/div\u003E\n                        \u003Cdiv class=\u0022mt-5 text-justify\u0022\u003E\n                                      \u003Cspan\u003Enon\u003C\/span\u003E\n                      \u003C\/div\u003E\n                  \u003C\/div\u003E\n      \u003C\/div\u003E\n    \u003Cdiv class=\u0022box col-md-6\u0022\u003E\n            \u003Cdiv class=\u0022field-spacing\u0022\u003E\n      \u003Cdiv class=\u0022field__label h3 dash\u0022\u003EPr\u00e9requis\u003C\/div\u003E\n                        \u003Cdiv class=\u0022mt-5 text-justify\u0022\u003E\n                                      \u003Cspan\u003E\u003Cp\u003E\u003Cstrong\u003EProperties of chemicals:\u003C\/strong\u003E Elements, Oxidation state, \u0026nbsp;\u003Cbr\u003E\nComplexation of cations and ligands,\u0026nbsp;\u003Cbr\u003E\n\u003Cstrong\u003EChemical reaction:\u003C\/strong\u003E stoichiometry, ICE chart\u0026nbsp;\u003Cbr\u003E\nMass Action Law, Gibbs free Energy, Chemical activity,\u003Cbr\u003E\n\u003Cstrong\u003EAcido-basic reaction,\u003C\/strong\u003E\u003Cbr\u003E\n\u003Cstrong\u003EDissolution-precipitation\u003C\/strong\u003E reaction, solubility,\u003Cbr\u003E\n\u003Cstrong\u003ERedox reaction,\u003C\/strong\u003E Nernst Law\u003C\/p\u003E\u003C\/span\u003E\n                      \u003C\/div\u003E\n                  \u003C\/div\u003E\n        \u003Cdiv class=\u0022field-spacing\u0022\u003E\n      \u003Cdiv class=\u0022field__label h3 dash\u0022\u003EProgramme \/ plan \/ contenus\u003C\/div\u003E\n                        \u003Cdiv class=\u0022mt-5 text-justify\u0022\u003E\n                                      \u003Cspan\u003E\u003Cp\u003EThe following sessions cover a wide range of the fuel cycle, including mining industry, cooling circuit of PWR, waste management, environmental speciation, f-elements.\u0026nbsp;\u003Cbr\u003E\n\u003Cstrong\u003ESession n\u00b01:\u003C\/strong\u003E Chemical equilibria, Acid\/base,\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u003Cbr\u003E\n\u003Cstrong\u003En\u00b02:\u003C\/strong\u003E Multiphasic Equilibria, High T\/P,\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u003Cbr\u003E\n\u003Cstrong\u003En\u00b03:\u003C\/strong\u003E Equilibrium shifts and complexation, \u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u003Cbr\u003E\n\u003Cstrong\u003En\u00b04:\u003C\/strong\u003E Activity coefficients, High salinities, \u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u003Cbr\u003E\n\u003Cstrong\u003En\u00b05:\u003C\/strong\u003E Oxydoreduction \u0026amp; corrosion,\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u003Cbr\u003E\n\u003Cstrong\u003En\u00b06:\u003C\/strong\u003E Applications \u0026amp; scientific articles,\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u003Cbr\u003E\n\u003Cstrong\u003En\u00b07\u0026amp;8:\u003C\/strong\u003E Uranium chemistry,\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u0026nbsp;\u003Cbr\u003E\n\u003Cstrong\u003En\u00b09\u0026amp;10:\u003C\/strong\u003E Chemistry of Actinides.\u003C\/p\u003E\u003C\/span\u003E\n                      \u003C\/div\u003E\n                  \u003C\/div\u003E\n        \u003Cdiv class=\u0022field-spacing\u0022\u003E\n      \u003Cdiv class=\u0022field__label h3 dash\u0022\u003EObjectifs d\u0026#039;apprentissage\u003C\/div\u003E\n                        \u003Cdiv class=\u0022mt-5 text-justify\u0022\u003E\n                                      \u003Cspan\u003E\u003Cp\u003EThe objective is to describe the mechanisms driving speciation in solution chemistry and introduce to a numerical tool simulating chemical systems. Classical physico-chemical concepts are reviewed: thermodynamic equilibrium, reactivity, multi-phasic systems. Lectures go into more detail on these concepts and the underlying models \u0026amp; equations. Analytical reasoning allowing to put in an equation practical macroscopic variables which characterize an aqueous equilibrium are given. Training to new concepts \u0026amp; tools is based on exercises. The use of the scientific software PhreeqC, to calculate speciation, is also taught through tutorials. They illustrate the necessity of numerical tools to describe real systems, importance of thermodynamic databases, and limitations of calculations.\u003C\/p\u003E\u003C\/span\u003E\n                      \u003C\/div\u003E\n                  \u003C\/div\u003E\n        \u003Cdiv class=\u0022field-spacing\u0022\u003E\n      \u003Cdiv class=\u0022field__label h3 dash\u0022\u003EOrganisation g\u00e9n\u00e9rale et modalit\u00e9s p\u00e9dagogiques\u003C\/div\u003E\n                        \u003Cdiv class=\u0022mt-5 text-justify\u0022\u003E\n                                      \u003Cspan\u003E\u003Cp\u003EFour different teachers are giving the lectures. After session n\u00b01 which includes introduction and prerequisite verification, the order might change depending speakers\u0027 timetables and availability.\u003C\/p\u003E\n\u003Cp\u003ESessions are given in a computer room from INSTN (Saclay). They\u0026nbsp;include a lecture dedicated to a specific topic. In addition, most of the session include the use of PhreeqC software, though practical \u0026amp; I.T. exercises. The aim is to apply concept learned during the lecture, illustrate the interest of the numerical tool and practice its operation.\u003C\/p\u003E\u003C\/span\u003E\n                      \u003C\/div\u003E\n                  \u003C\/div\u003E\n                        \u003Cdiv class=\u0022field-spacing\u0022\u003E\n      \u003Cdiv class=\u0022field__label h3 dash\u0022\u003EBibliographie\u003C\/div\u003E\n                        \u003Cdiv class=\u0022mt-5 text-justify\u0022\u003E\n                                      \u003Cspan\u003E\u003Cp\u003E\u003Cstrong\u003EChimie Physique,\u003C\/strong\u003E \u003Cem\u003EAtkins, De Paula, Keepler\u003C\/em\u003E, 5e \u00e9d., deBoeck (\u003Cstrong\u003E2021)\u003C\/strong\u003E\u003Cbr\u003E\n\u003Cstrong\u003ERadiochemistry \u0026amp; Nuclear Chemistry,\u003C\/strong\u003E \u003Cem\u003EG.R. Choppin, J. Rydberg, J.-O. Liljenzin, C. Ekberg,\u003C\/em\u003E 4th ed., Academic Press (\u003Cstrong\u003E2013)\u003C\/strong\u003E\u003Cbr\u003E\n\u003Cstrong\u003ELanthanide and Actinide Chemistry,\u003C\/strong\u003E \u003Cem\u003ES. Cotton,\u003C\/em\u003E Inorganic Chemistry, Wiley (\u003Cstrong\u003E2006)\u003C\/strong\u003E\u003C\/p\u003E\n\u003Cp\u003E\u003Cstrong\u003EKersting\u003C\/strong\u003E et al., Nature 397, 56-59 \u003Cstrong\u003E(1999)\u003C\/strong\u003E\u003Cbr\u003E\n\u003Cstrong\u003EJones\u003C\/strong\u003E et al., Applied Rad.\u0026nbsp;\u0026amp; Isotopes, 57, 159-165 \u003Cstrong\u003E(2002)\u003C\/strong\u003E\u003Cbr\u003E\n\u003Cstrong\u003ETasi\u003C\/strong\u003E et al., Applied Geochem., 98, 247-264 \u003Cstrong\u003E(2018)\u003C\/strong\u003E\u003Cbr\u003E\n\u003Cstrong\u003EDisdier\u003C\/strong\u003E et al., Chemosphere, 304, 135155 \u003Cstrong\u003E(2022)\u003C\/strong\u003E\u003Cbr\u003E\n\u003Cstrong\u003EReiller\u003C\/strong\u003E, P. Chemosphere, 350, 141049 \u003Cstrong\u003E(2024)\u003C\/strong\u003E\u003C\/p\u003E\u003C\/span\u003E\n                      \u003C\/div\u003E\n                  \u003C\/div\u003E\n        \u003Cdiv class=\u0022field-spacing\u0022\u003E\n      \u003Cdiv class=\u0022field__label h3 dash\u0022\u003ENature de l\u0026#039;\u00e9valuation\u003C\/div\u003E\n                        \u003Cdiv class=\u0022mt-5 text-justify\u0022\u003E\n                                      \u003Cspan\u003EEvaluation Continue non Int\u00e9grale\u003C\/span\u003E\n                      \u003C\/div\u003E\n                  \u003C\/div\u003E\n      \u003C\/div\u003E\n  \u003C\/div\u003E\n\u003C\/div\u003E\n","settings":null}]